Synthesis of substituted [3]dendralenes and their unique cycloaddition reactions.
نویسندگان
چکیده
Dimethylsulfonium methylide mediated olefination of 2-phenylethenylidene phosphonoacetate followed by the Horner-Wadsworth-Emmons reaction with aromatic aldehydes provided access to reactive 1,5-diaryl-2-ethoxycarbonyl [3]dendralenes which in situ underwent Diels-Alder cyclodimerisation leading to highly functionalised cyclohexenes with very high regio- and stereoselectivity.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 47 38 شماره
صفحات -
تاریخ انتشار 2011